Thermal density fluctuations in polymer glasses
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چکیده
منابع مشابه
Physical aging in polymer glasses.
Physical aging refers to structural relaxation of the glassy state toward the metastable equilibrium amorphous state, and it is accompanied by changes in almost all physical properties. These changes, which must be taken into account in the design, manufacture, and use of glassy polymer materials and devices, present a daunting challenge to theorists.
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Owing to the kinetic nature of the glass transition, the ability to significantly alter the properties of amorphous solids by the typical routes to the vitreous state is restricted. For instance, an order of magnitude change in the cooling rate merely modifies the value of the glass transition temperature (T(g)) by a few degrees. Here we show that matrix-assisted pulsed laser evaporation (MAPLE...
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Structural rejuvenation in metallic glasses by a thermal process (i.e. through recovery annealing) was investigated experimentally and theoretically for various alloy compositions. An increase in the potential energy, a decrease in the density, and a change in the local structure as well as mechanical softening were observed after thermal rejuvenation. Two parameters, one related to the anneali...
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We develop a field-theoretical description of dynamical heterogeneities and fluctuations in supercooled liquids close to the (avoided) MCT singularity. Using quasi-equilibrium arguments, we eliminate time from the description and we completely characterize fluctuations in the beta regime. We identify different sources of fluctuations and show that the most relevant ones are associated to variat...
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ژورنال
عنوان ژورنال: Journal of Polymer Science: Polymer Physics Edition
سال: 1981
ISSN: 0098-1273,1542-9385
DOI: 10.1002/pol.1981.180190812